Babe Who Never Lied | Arrange The Compounds In Order Of Decreasing Pka, Highest First.?
This resulted in lots of longer-fill entries involving some less common words and phrases. Trying to get back to the puzzle page? Ernie ELS (10D: 1994 P. G. A.
- Arrange the compounds in order of decreasing pka highest first element
- Arrange the compounds in order of decreasing pka highest first round
- Arrange the compounds in order of decreasing pka highest first class
A brig has two square-rigged masts, and is not (always) actually a BRIGANTINE, according to The New York Times, writing about a colonial-era ship excavated in Lower Manhattan. I have no way of knowing what's coming from the NYT, but the broader world of crosswords looks very bright, and that is sustaining. This is my 49th Sunday Times puzzle and for the first time I can say I had a glut of possible theme entries. You gotta do better than this. The word RESELL has No Such Connotation. The timing of this puzzle, vis-à-vis the government shutdown, is an unfortunate coincidence; our lineup is scheduled and set so far in advance that this kind of juxtaposition can happen, and I hope that nobody is dismayed. Green paint (n. )— in crosswords, a two-word phrase that one can imagine using in conversation, but that is too arbitrary to stand on its own as a crossword answer (e. Babe who never lied - crossword clue. g. SOFT SWEATER, NICE CURTAINS, CHILI STAIN, etc.
16D: I was absolutely taken in by this clue — read right over Feburary, which is next month MISSPELLED. Of course the parameter of matching word lengths for symmetry also went into the choices. SNOW ANGELS (28A: Things kids make in the winter). This is like cluing HOUSE as [Igloo]. Relative difficulty: Easy-Medium (normal Tuesday time, but it's 16 wide, so... must've been easier than normal, by a bit). 72A: I was briefly flummoxed by the clue here and looked for a question like "Where were you, " that would have been in response, or something like "Am I late? Babe who never lied crossword club.com. " Someone who works with an audience. 69D: Last seen in 1985 and another addition to the seafaring word bank we go to now and then, a BRIGANTINE has two masts, yes, but apparently only one is square-rigged. This is one of those great party-size themes that we encounter now and then on a Sunday, where there are piles of examples, as evidenced by Mr. Ross's notes below, and which hopefully inspires your own inventions once you've grasped the concept.
However, there are several problems. For example, at 22A, we have an "Unemployed salon worker" — think beauty shop, here, and you'll get an out-of-work or DISTRESSED HAIRDRESSER, a coiffeur who's been dis-tressed. And here: I'll stick a PayPal button in here for the mobile users. BUT... the biggest problem here is the fill, which is painful in many, many places. Today was a day when my mental repository of names came up short, so I struggled with BEAMON, CULP, THIEU and a couple of others; I did appreciate solving BABE and then getting THE BAMBINO, and I'll take any reference to LASSIE that I can get, the cleverer the better. Whatever happens, this blog will remain an outpost of the Old Internet: no ads, no corporate sponsorship, no whistles and bells. Babe who never lied. I hear Florida's nice.
Today's puzzle is Randolph Ross's 49th Sunday contribution (he's made 110 puzzles, according to, in total). That's one shy of his Sunday golden jubilee, and it puts him in fine company. INTERIOR DESIGNER, and it can't have been easy to embed that many *well-known* designers names inside two-word phrases. I have no interest in cordoning it off, nor do I have any interest in taking advertising. Try 83A, the "Unemployed loan officer" — aptly, a DISTRUSTED BANKER. 54 Matthews St. Binghamton NY 13905.
Moving from interior design to fashion design... just doesn't have pop. Follow Rex Parker on Twitter and Facebook]. It's certainly a compliment of the highest order and should be used as such more often — or would that cheapen it? They each define a person with a particular career, who has been removed from that particular career; their specific state of unemployment can be expressed as a pun. Or my favorite, at 100A, the "Unemployed rancher, " or DERANGED CATTLEMAN, which made me think so much of this old song, for some reason. The idea is very simple: if you read the blog regularly (or even semi-regularly), please consider what it's worth to you on an annual basis and give accordingly. Signed, Rex Parker, King of CrossWorld. THEME: INTERIOR DESIGNER (41A: Elle Decor reader... or any of the names hidden in 18-, 28-, 52- and 66-Across) —there are *fashion* DESIGNERs in the INTERIOR of every theme answer: Theme answers: - FARM ANIMALS (18A: Most of the leading characters in "Babe"). I was inspired by a slightly related joke category: "Old___ never die, they just …" e. g., "Old cashiers never die, they just check out. RARE GEM, which has never appeared in a Times puzzle before, just came to me and helped complete a difficult area. I chose the seven in this puzzle because they each had adjectives that had to do with being fired or quitting. Alex Rodriguez aka A-ROD (69A: Youngest player ever to hit 500 home runs, familiarly).
It's an easy Tuesday puzzle; we shouldn't be seeing even one of those answers, let alone all of them. Some very brief entries were gotchas, like EPA (I thought Carter set up this agency) and BAA, of all things, simply because I'd only thought of cotes as housing doves. A few particular entries that helped me complete this grid. Yes, we do have to think of it literally (designer's name physically situated in the "interior" of the theme phrase), and that is different, but we stay firmly in the realm of fashion / design. If you're feeling at all distempered right now, the rest of the entries include: Someone who works with nails. There are seven theme entries today, running across at 22, 29, 46, 63, 83, 100 and 111. Once we reached into the 70s and 80s with BEEPERS, entertaining UTAHANS and MCDLTS, I was on a bit firmer ground. 90A: A shop rule like 'No returns' is still a common CAVEAT. EYE INJURYs are real, but would you really buy EYE INJURY in your puzzle? I might accept HEAD or NECK or BRAIN INJURY as a stand-alone "body part INJURY" phrase, but all other body parts feel arbitrary. Since these theme entries were on the long side I was restricted to seven; usually I like eight or nine theme entries.
Arrange the compounds in order of decreasing pKa; highest first. Rank these acids according to their expected pKa values. A behaves had chlorine that was close to the leak. Due the the +I effect of -CH 3 towards the C atom with the ketone group, Hence, - Methylterbutylketone, due to its 3 -CH 3 groups, will be least reactive. Therefore, its pKa value is higher than that of salicylic acid. In the determination of the acidity of an organic compound, the most important thing to consider is the stability of the conjugate base formed.
Arrange The Compounds In Order Of Decreasing Pka Highest First Element
This problem has been solved! The increasing order of stability of the conjugate bases is the following: And therefore, the decreasing order of. How would you arrange the following compounds in order of decreasing pka: ClCH2CH2OH, CH3CH2OH, and Cl2CHCH2OH? Study carbonyl group examples. The N in -NH 2 OH will share its electrons with the C atom. Our experts can answer your tough homework and study a question Ask a question. Try Numerade free for 7 days. Acetaldehyde, due to the presence of only one -CH 3 group will be most reactive towards -NH 2 OH. Highest pKaCH3CHzNHzFCHZCHZCOOHCH:CHZCOOHCH;CHZOHLowest pKaThe…. Get 5 free video unlocks on our app with code GOMOBILE. Create an account to get free access. Hence, Benzoic acid will have the highest boiling point, followed by Ethanoic Acid and then Ethanol. C) ethanol, ethanoic acid, benzoic acid (boiling point).
Arrange The Compounds In Order Of Decreasing Pka Highest First Round
The stability of this conjugate base is mainly determined mainly through substituent effects and presence of resonance stabilization. Question: Rank these compounds in order of increasing pKa. He left town and you did the same, will that be a dig? Ranking in order of increasing pKa: The stability of the conjugate base depends on the number of resonance structures it has. Start with the highest pKa as numberCH3CH3H2NCH3HOCH3<….
In salicylic acid, there is one -COOH group and an -OH group. We have to know that there are reasons that make the hydrogen atoms that are in some compounds to be more labile than the hydrogen atoms in other compounds and this is largely as a result of the inductive effect. By clicking Sign up you accept Numerade's Terms of Service and Privacy Policy. We know that the pKa has to do with the dissociation of the acidic hydrogen in a compound. The increasing order of acidity is the following: This order is based on the stability of the corresponding conjugate bases of the mentioned acids. B) Acetaldehyde, Acetone, Methyl tert butyl ketone (reactivity towards NH2OH). Answered step-by-step.
Arrange The Compounds In Order Of Decreasing Pka Highest First Class
The acidic hydrogen is the hydrogen that is easily lost in a reaction. The increasing order of acidity will reflect the decreasing order of. The order of decreasing PKa for the compounds is; 1). In benzoic acid, there is only one -COOH group. Explanation: In general the higher the acid, the higher the value of. C) Ethanol Try it nowCreate an account. Hence, it has the highest acidity and lowest pKa value. Boiling point of a substance is the temperature at which force of attraction and bonds between molecules break and allow free movement of molecules. We can also call this hydrogen atom a labile or even a reactive hydrogen atom. Select the compound that has lowest pKa:COzHCOzHCH; COOHCOzH. The presence of the chlorine atom(s) in the structure of the acid will stabilize the negative charge on the oxygen of the conjugate base by inductive effect since the chlorine atom is an electronegative element. Hence phenol has the lowest acidity and highest pKa value due to its single -OH group. He said that there was a leak in the box. The pKa value of an acid is inversely dependent on its acidity and/or its stability. Thus the withdrawal of the electron density is a key factor in the classification of the compounds. The more stable the conjugate base the stronger the acid. This will be cool, and you as well. Briefly explain your choice_'.